57903
Aldrich
(Iodomethyl)trimethylsilane
purum, ≥99.0% (GC)
| Synonym: | (Trimethylsilyl)methyl iodide |
| CAS Number: | 4206-67-1 |
| Linear Formula: | (CH3)3SiCH2I |
| Molecular Weight: | 214.12 |
| Beilstein Registry Number: | 1731485 |
| EC Number: | 224-123-6 |
| MDL number: | MFCD00001077 |
| PubChem Substance ID: | 24880966 |
Description
| Other Notes | Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes1,2; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions3 |
Properties
| grade | purum |
| assay | ≥99.0% (GC) |
| refractive index | n |
| n | |
| bp | 139-141 °C(lit.) |
| density | 1.443 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | UN2924 3/PG 3 |
| WGK Germany | 3 |
| Flash Point(F) | 84.2 °F |
| Flash Point(C) | 29 °C |
References
| Cited Reference | 1. E. Vedejs et al. J. Org. Chem. 50, 2170, (1985) |
| 2. I. Fleming, I. Paterson Synthesis, 446, (1979) | |
| 3. E. Vedejs, F.G. West J. Org. Chem. 48, 4773, (1983) | |
| reference | D. Seyferth et al. J. Org. Chem. 42, 3104, (1977) |
| Beilstein | Beil. 4,IV,3878 |
| Aldrich MSDS 1, 1099:C / Corp MSDS 1 (1), 2002:D / FT-IR 2 (3), 4346:C / FT-IR 1 (2), 1100:C / IR-Spectra (3), 1539:G / NMR-Reference 2 (2), 985:A / RegBook 1 (2), 2955:F / Structure Index 1, 467:D:8 / Vapor Phase 3, 1628:A |
